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The gods are fickle creatures and if you desire to get closer to them with a higher level of devotion, this is the next step after worshipping. As a result of becoming devoted, your enhanced statistic bonuses will be modified in conjunction with your god's biases. Please note, you will not be able to train more/less with this change. It simply affects how high or low you can go in regards to magical enhancements such as spells and magical item bonuses. This can be removed with the unworship command at the same time you decide to stop worshipping your god.
Devotion only affects max stats and thus anything that is affected by those stats. Things like spell duration, spell AC bonus, and XP bonus are strictly tied to worship.
See also Worship.